Salt-assisted combustion synthesis of cobalt ferrite nanoparticles; magnetic properties and cation distribution measurement by XRD analysis

Document Type : Research Paper

Authors

Faculty of Materials Science and Engineering, K. N. Toosi University of Technology, Tehran, Iran.

Abstract

Current study represents the effect of the size and synthesis method on the cation distribution of cobalt ferrite nanoparticles and on the magnetic properties. The nanoferrites have been synthesized through sol-gel auto-combustion method using metal nitrates as precursor and citrate as fuel. In order to obtain the fine and agglomerated-free particles, we have used salt-assisted combustion reaction method. Magnetic properties of the synthesized single phase cobalt ferrite nanoparticles are carried out using vibrating sample magnetometer (VSM) at room temperature. It has been observed that the coercivity and saturation magnetization of the samples reduced by adding salt. The transmission electron microscopy (TEM) confirms the finer nanoparticles formation from around 70-200 nm to 10-40 nm. Structural characterization is done by X-ray diffraction (XRD) and it confirms the spinel structure formation for the samples. The crystallite size and induced strain were derived from the XRD patterns by Williamson-Hall (W-H) method. The magnetic parameters were reduced by crystallite size reduction from 38.5 nm to 11 nm. The further analysis of XRD peaks is fulfilled using Rietveld refinement in order to explain the magnetic properties. The obtained Rietveld refined data allow us to measure the distribution of cations within the available octahedral and tetrahedral sites.

Keywords

References

1.            Wang G, Wang H, Bai J. Preparation and electrochemical evaluation of manganese ferrite spheres as anode materials for half and full lithium-ion batteries. Journal of Alloys and Compounds. 2015;627:174-81.
2.            Sun X, Zhu X, Yang X, Sun J, Xia Y, Yang D. CoFe 2 O 4 /carbon nanotube aerogels as high performance anodes for lithium ion batteries. Green Energy & Environment. 2017;2(2):160-7.
3.            Hankiewicz JH, Stoll JA, Stroud J, Davidson J, Livesey KL, Tvrdy K, et al. Nano-sized ferrite particles for magnetic resonance imaging thermometry. Journal of Magnetism and Magnetic Materials. 2019;469:550-7.
4.            Zamani M, Naderi E, Aghajanzadeh M, Naseri M, Sharafi A, Danafar H. Co1−XZnxFe2O4 based nanocarriers for dual-targeted anticancer drug delivery: Synthesis, characterization and in vivo and in vitro biocompatibility study. Journal of Molecular Liquids. 2019;274:60-7.
5.            Vamvakidis K, Mourdikoudis S, Makridis A, Paulidou E, Angelakeris M, Dendrinou-Samara C. Magnetic hyperthermia efficiency and MRI contrast sensitivity of colloidal soft/hard ferrite nanoclusters. Journal of Colloid and Interface Science. 2018;511:101-9.
6.            Shahjuee T, Masoudpanah SM, Mirkazemi SM. Coprecipitation Synthesis of CoFe2O4 Nanoparticles for Hyperthermia. Journal of Ultrafine Grained and Nanostructured Materials. 2017 Dec 1;50(2):105-10.
7.            Shanmugavel T, Raj SG, Rajarajan G, Kumar GR, Boopathi G. Single Step Synthesis and Characterisation of Nanocrystalline Cobalt Ferrite by Auto-Combustion Method. Materials Today: Proceedings. 2015;2(4-5):3605-9.
8.            Sutka A, Mezinskis G. Sol-gel auto-combustion synthesis of spinel-type ferrite nanomaterials. Frontiers of Materials Science. 2012;6(2):128-41.
9.            Zhang X, Jiang W, Song D, Sun H, Sun Z, Li F. Salt-assisted combustion synthesis of highly dispersed superparamagnetic CoFe2O4 nanoparticles. Journal of Alloys and Compounds. 2009;475(1-2):L34-L7.
10.          Chen W, Li F, Yu J. Salt-assisted combustion synthesis of highly dispersed perovskite NdCoO3 nanoparticles. Materials Letters. 2007;61(2):397-400.
11.          Najmoddin N, Beitollahi A, Kavas H, Majid Mohseni S, Rezaie H, Åkerman J, et al. XRD cation distribution and magnetic properties of mesoporous Zn-substituted CuFe2O4. Ceramics International. 2014;40(2):3619-25.
12.          Kumar L, Kumar P, Narayan A, Kar M. Rietveld analysis of XRD patterns of different sizes of nanocrystalline cobalt ferrite. International Nano Letters. 2013;3(1).
13.          Levy D, Pavese A, Hanfland M. Phase transition of synthetic zinc ferrite spinel (ZnFe 2 O 4 ) at high pressure, from synchrotron X-ray powder diffraction. Physics and Chemistry of Minerals. 2000;27(9):638-44.
14.          Pourgolmohammad B, Masoudpanah SM, Aboutalebi MR. Synthesis of CoFe 2 O 4 powders with high surface area by solution combustion method: Effect of fuel content and cobalt precursor. Ceramics International. 2017;43(4):3797-803.
15.          Peddis D, Yaacoub N, Ferretti M, Martinelli A, Piccaluga G, Musinu A, et al. Cationic distribution and spin canting in CoFe2O4nanoparticles. Journal of Physics: Condensed Matter. 2011;23(42):426004.
16.          Singh S, Khare N. Defects/strain influenced magnetic properties and inverse of surface spin canting effect in single domain CoFe2O4 nanoparticles. Applied Surface Science. 2016;364:783-8.
17.          Pubby K, Meena SS, Yusuf SM, Bindra Narang S. Cobalt substituted nickel ferrites via Pechini’s sol–gel citrate route: X-band electromagnetic characterization. Journal of Magnetism and Magnetic Materials. 2018;466:430-45.
18.          Mozaffari S, Li W, Thompson C, Ivanov S, Seifert S, Lee B, et al. Colloidal nanoparticle size control: experimental and kinetic modeling investigation of the ligand–metal binding role in controlling the nucleation and growth kinetics. Nanoscale. 2017;9(36):13772-85.
19.          Li W, Ivanov S, Mozaffari S, Shanaiah N, Karim AM. Palladium Acetate Trimer: Understanding Its Ligand-Induced Dissociation Thermochemistry Using Isothermal Titration Calorimetry, X-ray Absorption Fine Structure, and 31P Nuclear Magnetic Resonance. Organometallics. 2018;38(2):451-60.
20.          Mozaffari S, Li W, Thompson C, Ivanov S, Seifert S, Lee B, et al. Ligand-Mediated Nucleation and Growth of Palladium Metal Nanoparticles. Journal of Visualized Experiments. 2018(136).
21.          Irfan H, Racik K M, Anand S. Microstructural evaluation of CoAl2O4 nanoparticles by Williamson–Hall and size–strain plot methods. Journal of Asian Ceramic Societies. 2018;6(1):54-62.
22.          Jamil MT, Ahmad J, Bukhari SH, Saleem M. Effect of Re and Tm-site on morphology structure and optical band gap of ReTmO3 (Re: La, Ce, Nd, Gd, Dy, Y and Tm: Fe, Cr) prepared by sol-gel method. Revista Mexicana de Física. 2018;64(4):381.
23.          Augustin M, Balu T. Estimation of Lattice Stress and Strain in Zinc and Manganese Ferrite Nanoparticles by Williamson–Hall and Size-Strain Plot Methods. International Journal of Nanoscience. 2017;16(03):1650035.
24.          Chinnasamy CN, Jeyadevan B, Shinoda K, Tohji K, Djayaprawira DJ, Takahashi M, et al. Unusually high coercivity and critical single-domain size of nearly monodispersed CoFe2O4 nanoparticles. Applied Physics Letters. 2003;83(14):2862-4.
25.          Shin T-H, Choi Y, Kim S, Cheon J. Recent advances in magnetic nanoparticle-based multi-modal imaging. Chemical Society Reviews. 2015;44(14):4501-16.
 
Journal of Ultrafine Grained and Nanostructured Materials
Volume 52, Issue 1
June 2019
Pages 69-77

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History

  • Receive Date: 26 February 2019
  • Revise Date: 08 April 2019
  • Accept Date: 23 April 2019

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