Review on Various Synthesis Methods of Bismuth Telluride Nanoparticles

Document Type : Review Paper


1 Department of Physics Vimala College ( Autonomous) , Thrissur

2 Department of Physics Vimala College ( AUtonomous) , Thrissur


The investigations on the synthesis and various applications of the bismuth telluride (Bi2Te3) nanoparticle have gained great attention in the present era due to its wide range of applications. Continued efforts are made by researchers to develop devices based on nanostructured materials. In this review paper, different methods for the synthesis of nanostructured Bi2Te3 are presented. Dependence of properties based on the synthesis methods is reviewed as well. Both physical and chemical methods are applied to get different forms of nano compounds. The merits and demerits of both methods are also explained in this review. Briefly, the different synthesis methods of bismuth telluride nanoparticles and its unique properties are critically discussed in this overview.


  1. Shi Y, Sturm C, Kleinke H. Chalcogenides as thermoelectric materials. Journal of Solid State Chemistry. 2019;270:273-9.
  2. Mamur H, Bhuiyan MRA, Korkmaz F, Nil M. A review on bismuth telluride (Bi2Te3) nanostructure for thermoelectric applications. Renewable and Sustainable Energy Reviews. 2018;82:4159-69.
  3. Kim J-H, Choi J-Y, Bae J-M, Kim M-Y, Oh T-S. Thermoelectric Characteristics of n-Type Bi<sub>2</sub>Te<sub>3</sub> and p-Type Sb<sub>2</sub>Te<sub>3</sub> Thin Films Prepared by Co-Evaporation and Annealing for Thermopile Sensor Applications. MATERIALS TRANSACTIONS. 2013;54(4):618-25.
  4. Vieira EMF, Figueira J, Pires AL, Grilo J, Silva MF, Pereira AM, et al. Enhanced thermoelectric properties of Sb2Te3 and Bi2Te3 films for flexible thermal sensors. Journal of Alloys and Compounds. 2019;774:1102-16.
  5. Goncalves LM, Alpuim P, Min G, Rowe DM, Couto C, Correia JH. Optimization of Bi2Te3 and Sb2Te3 thin films deposited by co-evaporation on polyimide for thermoelectric applications. Vacuum. 2008;82(12):1499-502.
  6. Gonçalves LM, Couto C, Alpuim P, Rowe DM, Correia JH. Thermoelectric Properties of Bi<sub>2</sub>Te<sub>3</sub>/Sb<sub>2</sub>Te<sub>3</sub> Thin Films. Materials Science Forum. 2006;514-516:156-60.
  7. Takashiri M, Shirakawa T, Miyazaki K, Tsukamoto H. Fabrication and characterization of bismuth–telluride-based alloy thin film thermoelectric generators by flash evaporation method. Sensors and Actuators A: Physical. 2007;138(2):329-34.
  8. Takashiri M, Hamada J. Bismuth antimony telluride thin films with unique crystal orientation by two-step method. Journal of Alloys and Compounds. 2016;683:276-81.
  9. Bahabri F. Investigation of the structural and optical properties of bismuth telluride (Bi2Te3) thin films. Life Sci. J. 2012;9(1):290-4.
  10. Pradyumnan PP. Thermoelectric properties of Bi 2 Te 3 and Sb 2 Te 3 and its bilayer thin films.
  11. Elahi SM, Nazari H, Dejam L, Gorji HR. Studying Thermoelectric Power Behaviors of Bi&lt;sub&gt;2&lt;/sub&gt;Te&lt;sub&gt;3&lt;/sub&gt; Nanoparticles Prepared by Thermal Evaporation. Open Journal of Applied Sciences. 2016;06(06):336-42.
  12. Das JK, Nahid MA. Electrical Properties of Thermal Evaporated Bismuth Telluride Thin Films. International Journal of Thin Films Science and Technology. 2015 Jan 1;4(1):13.
  13. Lin JM, Chen YC, Lin CP. Annealing effect on the thermoelectric properties of Bi2Te3 thin films prepared by thermal evaporation method. Journal of nanomaterials. 2013 Nov;2013.
  14. Elahi SM, Taghizadeh A, Hadizadeh A, Dejam L. Effect of Thickness and Annealing on Structural and Optical Properties of Bi2Te3 Thin Films Prepared from Bi2Te3 Nanoparticels. International Journal of Thin Films Science and Technology. 2014;3(1):13-8.
  15. Deng Y, Zhang Z, Wang Y, Xu Y. Preferential growth of Bi2Te3 films with a nanolayer structure: enhancement of thermoelectric properties induced by nanocrystal boundaries. Journal of Nanoparticle Research. 2012;14(4).
  16. Bourgault D, Giroud-Garampon C, Caillault N, Carbone L. Thermoelectrical devices based on bismuth-telluride thin films deposited by direct current magnetron sputtering process. Sensors and Actuators A: Physical. 2018;273:84-9.
  17. Jin Q, Shi WB, Qiao JX, Sun C, Tai KP, Lei H, et al. Enhanced thermoelectric properties of bismuth telluride films with in-plane and out-of-plane well-ordered microstructures. Scripta Materialia. 2016;119:33-7.
  18. Zhou Y, Li L, Tan Q, Li J-F. Thermoelectric properties of Pb-doped bismuth telluride thin films deposited by magnetron sputtering. Journal of Alloys and Compounds. 2014;590:362-7.
  19. Taylor A, Mortensen C, Rostek R, Nguyen N, Johnson DC. Vapor Annealing as a Post-Processing Technique to Control Carrier Concentrations of Bi2Te3 Thin Films. Journal of Electronic Materials. 2010;39(9):1981-6.
  20. Girish Mahajan A, Deosarkar M, Panmand R. Study and Characterization of Thermoelectric Material (TE) Bismuth Antimony Telluride. Journal of Material Science & Engineering. 2018;07(04).
  21. Deng Y, Nan C-W, Wei G-D, Guo L, Lin Y-h. Organic-assisted growth of bismuth telluride nanocrystals. Chemical Physics Letters. 2003;374(3-4):410-5.
  22. Urkude RR, Patil PT, Kondawar SB, Palikundwar UA. Synthesis, Characterization and Electrical Properties of a Composite of Topological Insulating Material: Bi2Te3-PANI. Procedia Materials Science. 2015;10:205-11.
  23. Zhao XB, Zhang YH, Ji XH. Solvothermal synthesis of nano-sized La x Bi (2–x) Te 3 thermoelectric powders. Inorganic Chemistry Communications. 2004;7(3):386-8.
  24. Deng Y, Cui C-W, Zhang N-L, Ji T-H, Yang Q-L, Guo L. Fabrication of bismuth telluride nanotubes via a simple solvothermal process. Solid State Communications. 2006;138(3):111-3.
  25. Tongpeng S, Sarakonsri T, Chayasombat B, Boothroyd C, Thanachayanont C. Microstructure and Thermoelectric Properties of Bi2Te3 Nanoplates Prepared by Sol-gel Method.
  26. Michel S, Stein N, Schneider M, Boulanger C, Lecuire JM. Journal of Applied Electrochemistry. 2003;33(1):23-7.
  27. Lim S-K, Kim M-Y, Oh T-S. Thermoelectric properties of the bismuth–antimony–telluride and the antimony–telluride films processed by electrodeposition for micro-device applications. Thin Solid Films. 2009;517(14):4199-203.
  28. Scidone L, Diliberto S, Stein N, Boulanger C, Lecuire JM. Electroless method for Bi2Te3 film deposition. Materials Letters. 2005;59(7):746-8.
  29. Zhu W, Yang JY, Hou J, Gao XH, Bao SQ, Fan XA. Optimization of the formation of bismuth telluride thin film by using ECALE. Journal of Electroanalytical Chemistry. 2005;585(1):83-8.
  30. Zhu W, Yang J, Gao X, Hou J, Bao S, Fan X. Preparation of bismuth telluride thin film by electrochemical atomic layer epitaxy (ECALE). Frontiers of Chemistry in China. 2007;2(1):102-6.
  31. Kwon S-D, Kim J-S. MOCVD Growth of Thermoelectric BiSbTe3 Films on Surface-Treated Sapphire Substrates. Journal of the Korean Physical Society. 2009;54(4):1589-93.
  32. You H, Bae S-H, Kim J, Kim J-S, Park C. Deposition of Nanocrystalline Bi2Te3 Films Using a Modified MOCVD System. Journal of Electronic Materials. 2011;40(5):635-40.
  33. Kim HJ, Han M-K, Kim H-Y, Lee W, Kim S-J. Morphology Controlled Synthesis of Nanostructured Bi2Te3. Bulletin of the Korean Chemical Society. 2012;33(12):3977-80.
  34. Yu C, Zhang X, Leng M, Shaga A, Liu D, Chen F, et al. Preparation and thermoelectric properties of inhomogeneous bismuth telluride alloyed nanorods. Journal of Alloys and Compounds. 2013;570:86-93.
  35. Kim H-J, Lee K-J, Kim S-J, Han M-K. A Simple and Quick Chemical Synthesis of Nanostructured Bi2Te3, Sb2Te3, and BixSb2-xTe3. Bulletin of the Korean Chemical Society. 2010;31(5):1123-7.
  36. Kim K, Lee HM, Kim DW, Kim KJ, Lee GG, Ha GH. Bismuth-telluride Thermoelectric Nanoparticles Synthesized by Using a Polyol Process. Journal of the Korean Physical Society. 2010;57(4(1)):1037-40.
  37. Gupta S, Neeleshwar S, Kumar V, Chen YY. Synthesis Of Bismuth Telluride Nanostructures By refluxing Method. Advanced Materials Letters. 2012;3(1):50-4.
  38. Zhang C, de la Mata M, Li Z, Belarre FJ, Arbiol J, Khor KA, et al. Enhanced thermoelectric performance of solution-derived bismuth telluride based nanocomposites via liquid-phase Sintering. Nano Energy. 2016;30:630-8.