Ni-Al2O3 Nanocomposite with High Specific Surface Area Synthesized by Mixture of Fuels through Solution Combustion

Document Type : Research Paper

Authors

1 Department of Materials Engineering, Faculty of Mechanic and Materials Engineering, Birjand University of Technology, Birjand, Iran

2 Department of Materials Science and Engineering, Engineering Faculty, Ferdowsi University of Mashhad, Mashhad, Iran

3 Department of Physics, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran

Abstract

This paper investigates the application of a mixture of three types of fuels, namely urea, glycine and hydrazine, for the synthesis of Ni-10 wt. % Al2O3 nanocomposite using the solution combustion method. Nickel and aluminum nitrates are used as an oxidizer. The fuels are used at two different fuel to oxidizer ratios. DSC-TGA diagrams prove hydrazine-nitrate reaction system can ignite before nitrate decomposition in contrary to urea-nitrate and glycine-nitrate systems. The results showed synthesized alumina at combustion temperatures less than 500 ºC is amorphous and the combustion temperatures more than 600 ºC made alumina crystalline. The measured surface area for the synthesized nanocomposite in air and less than 10 min was 207 m2 g-1. SEM and FESEM images prove the presence of small porosities in the synthesized nanocomposites. TEM image shows synthesized alumina in the nanocomposite has a mean particle size of less than 25 nm.

Keywords

References

  1. Wang H, Han W, Li X, Liu B, Tang H, Li Y. Solution Combustion Synthesis of Cr₂O₃ Nanoparticles and the Catalytic Performance for Dehydrofluorination of 1,1,1,3,3-Pentafluoropropane to 1,3,3,3-Tetrafluoropropene. Molecules (Basel, Switzerland). 2019;24(2):361.
  2. Xiao X, Zhang Z, Cai L, Li Y, Yan Z, Wang Y. The excellent catalytic activity for thermal decomposition of ammonium perchlorate using porous CuCo2O4 synthesized by template-free solution combustion method. Journal of Alloys and Compounds. 2019;797:548-57.
  3. Khaliullin SM, Zhuravlev VD, Bamburov VG, Khort AA, Roslyakov SI, Trusov GV, Moskovskikh DO. Effect of the residual water content in gels on solution combustion synthesis temperature. Journal of Sol-Gel Science and Technology. 2020 Feb;93(2):251-61.
  4. Potanin AY, Vorotilo S, Pogozhev YS, Rupasov SI, Lobova TA, Levashov EA. Influence of mechanical activation of reactive mixtures on the microstructure and properties of SHS-ceramics MoSi2–HfB2–MoB. Ceramics International. 2019;45(16):20354-61.
  5. Ortiz-Quiñonez J-L, Pal U, Villanueva MS. Structural, Magnetic, and Catalytic Evaluation of Spinel Co, Ni, and Co-Ni Ferrite Nanoparticles Fabricated by Low-Temperature Solution Combustion Process. ACS Omega. 2018;3(11):14986-5001.
  6. Xu C, Manukyan KV, Adams RA, Pol VG, Chen P, Varma A. One-step solution combustion synthesis of CuO/Cu2O/C anode for long cycle life Li-ion batteries. Carbon. 2019;142:51-9.
  7. Deganello F, Tyagi AK. Solution combustion synthesis, energy and environment: Best parameters for better materials. Progress in Crystal Growth and Characterization of Materials. 2018;64(2):23-61.
  8. Mukasyan AS, Dinka P. Novel approaches to solution-combustion synthesis of nanomaterials. International Journal of Self-Propagating High-Temperature Synthesis. 2007;16(1):23-35.
  9. Ianoş R, Tăculescu A, Păcurariu C, Lazău I. Solution Combustion Synthesis and Characterization of Magnetite, Fe3O4, Nanopowders. Journal of the American Ceramic Society. 2012;95(7):2236-40.
  10. González-Cortés SL, Imbert FE. Fundamentals, properties and applications of solid catalysts prepared by solution combustion synthesis (SCS). Applied Catalysis A: General. 2013;452:117-31.
  11. Kang W, Ozgur DO, Varma A. Solution Combustion Synthesis of High Surface Area CeO2 Nanopowders for Catalytic Applications: Reaction Mechanism and Properties. ACS Applied Nano Materials. 2018;1(2):675-85.
  12. Tarragó DP, Malfatti CdF, de Sousa VC. Influence of fuel on morphology of LSM powders obtained by solution combustion synthesis. Powder Technology. 2015;269:481-7.
  13. Vahdat Vasei H, Masoudpanah SM, Adeli M, Aboutalebi MR. Photocatalytic properties of solution combustion synthesized ZnO powders using mixture of CTAB and glycine and citric acid fuels. Advanced Powder Technology. 2019;30(2):284-91.
  14. Mirbagheri SA, Masoudpanah SM, Alamolhoda S. Structural and optical properties of ZnAl2O4 powders synthesized by solution combustion method: Effects of mixture of fuels. Optik. 2020;204:164170.
  15. Novitskaya E, Kelly JP, Bhaduri S, Graeve OA. A review of solution combustion synthesis: an analysis of parameters controlling powder characteristics. International Materials Reviews. 2021 Apr 3;66(3):188-214.
  16. Yilmaz E, Sonmez MS. The influence of process parameters on the chemical and structural properties of solution combustion prepared vanadium pentoxide. Materials Letters. 2020;261:127095.
  17. Li P, Hu X, Zhang Z, Wen M, Chen M, Yu B, et al. A series of Ni–Al2O3 catalysts derived from layered double hydroxides for vapor phase catalytic exchange between water and hydrogen. International Journal of Hydrogen Energy. 2021;46(63):32036-43.
  18. Muangnapoh T, Srimara P, Vas-Umnuay P. Template- and Magnetic Field-Free Chemical Reduction of Ni Nanochains for Ni-Al(2)O(3) Cermet Films: Growth Control, Characterization, and Application. ACS Omega. 2020;5(38):24584-91.
  19. Serdyukov SI, Kniazeva MI, Sizova IA, Zubavichus YV, Dorovatovskii PV, Maximov AL. A new precursor for synthesis of nickel-tungsten sulfide aromatic hydrogenation catalyst. Molecular Catalysis. 2021;502:111357.
  20. Cui C, Liu Y, Mehdi S, Wen H, Zhou B, Li J, et al. Enhancing effect of Fe-doping on the activity of nano Ni catalyst towards hydrogen evolution from NH3BH3. Applied Catalysis B: Environmental. 2020;265:118612.
  21. Patil KC, Aruna ST, Mimani T. Combustion synthesis: an update. Current Opinion in Solid State and Materials Science. 2002;6(6):507-12.
  22. Mekasuwandumrong O, Wongwaranon N, Panpranot J, Praserthdam P. Effect of Ni-modified α-Al2O3 prepared by sol–gel and solvothermal methods on the characteristics and catalytic properties of Pd/α-Al2O3 catalysts. Materials Chemistry and Physics. 2008;111(2-3):431-7.
  23. Tahmasebi K, Paydar MH. The effect of starch addition on solution combustion synthesis of Al2O3–ZrO2 nanocomposite powder using urea as fuel. Materials Chemistry and Physics. 2008;109(1):156-63.
  24. Deshpande K, Mukasyan A, Varma A. Direct Synthesis of Iron Oxide Nanopowders by the Combustion Approach:  Reaction Mechanism and Properties. Chemistry of Materials. 2004;16(24):4896-904.
  25. Avgouropoulos G, Ioannides T. Selective CO oxidation over CuO-CeO2 catalysts prepared via the urea–nitrate combustion method. Applied Catalysis A: General. 2003;244(1):155-67.
  26. Stewardson D. Design and Analysis of Experiments Design and Analysis of Experiments 5hEd by Douglas C Montgomery 2001 , John Wiley , New York . Hard-Bound, 684 pp ISBN 0 471 31649 0. MSOR Connections. 2001;1(1):15-6.
  27. Liu Y, Qin M-l, Zhang L, Jia B-r, Cao Z-q, Zhang D-z, et al. Solution combustion synthesis of Ni–Y2O3 nanocomposite powder. Transactions of Nonferrous Metals Society of China. 2015;25(1):129-36.
  28. D.R. Gaskell., Introduction to the Thermodynamics of Materials, 4th ed, Tylor and Francis Books, 2003.
  29. Samain L, Jaworski A, Edén M, Ladd DM, Seo D-K, Javier Garcia-Garcia F, et al. Structural analysis of highly porous γ-Al2O3. Journal of Solid State Chemistry. 2014;217:1-8.
  30. Nasiri H, Bahrami Motlagh E, Vahdati Khaki J, Zebarjad SM. Role of fuel/oxidizer ratio on the synthesis conditions of Cu–Al2O3 nanocomposite prepared through solution combustion synthesis. Materials Research Bulletin. 2012;47(11):3676-80.
  31. Yalamaç E, Trapani A, Akkurt S. Sintering and microstructural investigation of gamma–alpha alumina powders. Engineering Science and Technology, an International Journal. 2014;17(1):2-7.
  32. GarcÍa R, Hirata GA, McKittrick J. New combustion synthesis technique for the production of (InxGa1−x)2O3 powders: Hydrazine/metal nitrate method. Journal of Materials Research. 2001;16(4):1059-65.
  33. Patil KC, Hegde MS, Rattan T, Aruna ST. Chemistry of Nanocrystalline Oxide Materials: WORLD SCIENTIFIC; 2008 2008/09.
  34. Shehata F, Fathy A, Abdelhameed M, Moustafa SF. Preparation and properties of Al2O3 nanoparticle reinforced copper matrix composites by in situ processing. Materials & Design. 2009;30(7):2756-62.

 

Journal of Ultrafine Grained and Nanostructured Materials
Volume 55, Issue 2
December 2022
Pages 122-132

Files

History

  • Receive Date: 15 December 2021
  • Revise Date: 16 January 2022
  • Accept Date: 17 January 2022

Share

How to cite

Statistics