Journal of Ultrafine Grained and Nanostructured Materials

Journal of Ultrafine Grained and Nanostructured Materials

Nano-Hybrids Based on Surface Modified Reduced Graphene Oxide Nanosheets and Carbon Nanotubes and a Regioregular Polythiophene

Document Type : Research Paper

Authors
Samira Agbolaghi 1
Saleheh Abbaspoor 2
1 Chemical Engineering Department, Faculty of Engineering, Azarbaijan Shahid Madani University, Tabriz, Iran
2 Faculty of Polymer Engineering and Institute of Polymeric Materials, Sahand University of Technology, Tabriz, Iran
10.22059/jufgnsm.2018.01.08
Abstract
 
 
The multi-walled carbon nanotubes (CNTs) and reduced graphene oxide (rGO) nanosheets were functionalized with 2-hydroxymethyl thiophene (CNT-f-COOTh) and 2-thiophene acetic acid (rGO-f-TAA) and grafted with poly(3-dodecylthiophene) (CNT-g-PDDT and rGO-g-PDDT) to manipulate the orientation and patterning of crystallized regioregular poly(3-hexylthiophene) (P3HT). Distinct nano-hybrid structures including double-fibrillar (5.11−5.18 S/cm), shish-kebab (2.19−2.28 S/cm), and stem-leaf (6.96−7.51 S/cm) were developed using modified CNTs and P3HT. The most effective parameter on morphology of donor-acceptor supramolecules was the surface functionalization and grafting. The electrical conductivities of supramolecules based on P3HT and rGO, rGO-f-TAA, and rGO-g-PDDT ranged in 3.81−3.87, 3.91−3.95, and 10.67−10.70 S/cm, respectively. P3HT chains preferred to interact with their thiophene rings with bared rGO and CNT surfaces, resulting in a conventional face-on orientation. In P3HT/rGO-f-TAA and P3HT/CNT-f-COOTh supramolecular nanostructures patterned with P3HT, the orientation of P3HT chains changed from face-on to edge-on, originating from the strong interactions between the hexyl side chains of P3HTs and functional groups. Nano-hybrids based on grafted rGO demonstrated a patched-like morphology composed of flat-on P3HTs with main backbones perpendicular to the substrate. Based on the ultraviolet-visible and photoluminescence analyses, the flat-on orientation was the best for P3HT chains assembled onto CNT and rGO, which was acquired for CNT-g-PDDT and rGO-g-PDDT nano-hybrids.
Keywords
Carbon Nanotube
Reduced Graphene Oxide, Orientation, Grafting, Functionalization, Nano-hybrid
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Journal of Ultrafine Grained and Nanostructured Materials
Volume 51, Issue 1
June 2018
Pages 60-70

  • Receive Date 29 December 2017
  • Revise Date 28 February 2018
  • Accept Date 04 March 2018